I'm resurrecting this thread (along with 
this one that came after) because I'm still having problems.
At first I thought it was the "Save for Web".  Now I think it's a problem with my workspace itself.  I just realized that when I look in my color picker the colors are all wrong.  Instead of grays I get muddy/brownish gray tones.
For instance #808080 isn't a medium grey but rather a taupe-tinted grey.  This problem while working is having an adverse effect on the end result in my chops.  While working on them they seem to be the color I want and then when I save for web they are all drab and lifeless (like my latest contest entry's colors).  
Here's what the color picker looks like:
Better picker-upper:
If I screenshot that window and paste it into a .psd I see this:
See how, in the .psd, the blacks and grays are turned to browns?
HELP!
 
					
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Why I do believe it's pants-less o'clock! - Lar deSouza
”The mind is like a parachute, it doesn’t work if it isn’t open.”  - Frank Zappa
Created using photoshop and absolutely no talent. - reyrey